For me, there are 2.
The first one is Captain Quarsh Panaka. If you don’t remember him he was Padme’s security guard in The Phantom Menace, but did not return in Attack of the Clones because Hugh Quarshie did not want to reprise his role. So his character was replaced by Captain Gregar Typho. I think he should’ve appeared in The Clone Wars at some point because he was an essential character in TPM, and since he was supposed to be in AOTC but didn’t return because the actor didn’t want to come back, I think that him appearing in TCW would’ve been a good way to bring his character back.
The second one is San Hill, he should’ve appeared because he was the Chairman of the InterGalactic Banking Clan and a member of the Separatist Council. I think he should’ve definitely appeared in the InterGalactic Banking Clan related arcs. He should’ve been close to Nix Card, and you would think he would’ve been seen in the clan meetings. But for some reason he never appeared in the show.