I want to say Gideon, but it could be because of bias. Not exactly because of Mandalorian, but his other villainous role...at Los Pollos Hermanos, in New Mexico. Lol But he did have a pretty good setup as a threat, despite the disappointment Mando S3 was.
Hemlock may yet win the race, but it will depend on how The Bad Batch S3 plays out. That is presuming we don't see him in any future media afterward. Not to say we know for sure if he will die, or maybe live for the next inevitable animated series to come. We will see.